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DERVISEVIC, Muamer | DERVISEVIC, Esma | AZAK, Hacer | ÇEVİK, Emre | ŞENEL, Mehmet | YILDIZ, Hüseyin Bekir
In this paper, a novel amperometric xanthine (X) biosensor is constructed by xanthine oxidase (XOx) immobilization on the pencil graphite electrode (PGE). Xanthine oxidase is immobilized using glutaraldehyde (GA) on the electrochemically polymerized conducting polymer film. The detection of xanthine is based on its consumed amount due to the enzymatic reaction of xanthine oxidase. The effects of polymer thickness, applied potential, pH, and temperature were investigated and optimum parameters were found to be five cycles, +5 V, +0.5 V and 30 °C, respectively. Storage stability, operation stabi ...Daha fazlası
SAYIN, Serkan | AZAK, Hacer | YILDIZ, Hüseyin Bekir | ÇAMURLU, Pınar | UYSAL AKKUŞ, Gülderen | TOPPARE, Lale | ERSÖZ, Mustafa
Two novel calix[n]arene-adorned gold electrodes producing high photocurrent intensities were successfully constructed by embedding gold electrode surfaces with both P(4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)benzenamine) conducting polymer and 4-mercaptoboronic acid-functionalized semiconductor CdS nanoparticles to facilitate the binding of calix[n]arene sulfonic acids with nanoparticles. This structure enabled an electron transfer cascade that both induced effective charge separation and efficiently generated photocurrent. The prepared electrodes were used to generate photocurrent by relying o ...Daha fazlası
AZAK, Hacer | BARLAS, Fırat Barış | YILDIZ, Hüseyin Bekir | GÜLEÇ, Kadri | DEMİR, Bilal | ODACI DEMİRKOL, Dilek | TİMUR, Suna
Here, postfunctionalization and bioapplication of a π-conjugated polymer named 4-[4H-dithieno(3,2-b:2',3'-d)pyrrol-4-yl]aniline (DTP-aryl-NH2 ) are reported, which is successfully synthesized via electropolymerization onto the glassy carbon electrode. Folic acid (FA) is used to modify the amino functional polymer via N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride/N-hydroxysuccinimide chemistry for the further steps. The selective adhesion of folate receptor positive cells on the surface is followed by the electrochemical methods. Cyclic voltammetry and electrochemical impedance s ...Daha fazlası
TAŞÇI, Filiz | SAYIN, Serkan | AĞ SELECİ, Didem | DEMİR, Bilal | AZAK, Hacer | YILDIZ, Hüseyin Bekir | ODACI DEMİRKOL, Dilek | TİMUR, Suna
Aim: The development of calixarene based phenol biosensor. Methods: This study describes the application of a calixarene derivative, 5,17-diamino-25,27-bis(3-thiol-1-oxypropane)-26,28-dihydroxycalix[4]arene (HS-Calix-NH2) which has both amino and thiol functionalities, in the practical surface modifications for biomolecule binding. The structure of HS-Calix-NH2 allows easy inter-action with Au surface and one-step biomolecule immo-bilization. Self-assembled monolayers (SAMs) of p-amino-functionalized mercaptoalkylcalixarene (HS-Calix-NH2) were formed onto the Au electrode. Then, Laccase (Lac) ...Daha fazlası
AZAK, Hacer | YILDIZ, Hüseyin Bekir | ÇARBAŞ, Buket
Synthesis and electropolymerization of a new conjugated dithieno(3,2-b:20,30-d) pyrole (DTP) derivative, namely, 2-(2-(2-(4H-dithieno[3,2-b:20,30-d]pyrrol-4-yl)ethoxy)ethoxy)ethanamine, (DTP-alkoxy-NH2) monomer are presented. The electrochemical, spectroelectrochemical effects and biosensor capability towards to glucose oxidase enzyme of P(DTP-alkoxy-NH2) polymer fi lm are investigated in detail during the placement of alkoxy-NH2 functional unit in the polymer. Electrochemical and optical results between neutral and oxidized states of the polymer fi lm show that (P(DTP-alkoxy-NH2)) has reversibl ...Daha fazlası
AZAK, Hacer | KURBANOĞLU, Sevinç | YILDIZ, Hüseyin Bekir | ÖZKAN, Sibel Ayşıl
The synthesis of derivatives of dithionepyrrole is a hot subject that has been studied extensively. In this study, a novel approach for constructing different glucose biosensors using conducting polymers of 4-(4H-dithyinol[3,2-b:2′,3′-d]pyroll-4-yl)aniline and 4-(4H-dithyinol[3,2-b:2′,3′-d]pyroll-4-yl)-[1,1′-biphenyl]-4-amine is proposed. After the synthesis and characterizations of the dithionepyrrole type monomers, they were used in glucose biosensing applications. The surface of gold electrode was modified with mercaptoethane sulfonic acid and p-aminothiophenol functionalized gold nanoparti ...Daha fazlası
6698 sayılı Kişisel Verilerin Korunması Kanunu kapsamında yükümlülüklerimiz ve cerez politikamız hakkında bilgi sahibi olmak için alttaki bağlantıyı kullanabilirsiniz.