Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2’,3’-D) pyrrole derivative
YILDIZ, Hüseyin Bekir
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A novel alkoxy-bridged dithieno (3, 2-B:2’,3’-D) pyrrole (DTP) derivative was synthesized and its corresponding polymer poly(1,2-bis(2-(4H-dithieno[3,2-b:2’,3’-d]pyrrol-4-yl)ethoxy)ethane) (P(DTP-alkoxy-DTP)) was successfully obtained electrochemically. The eﬀects of alkoxy bridge in the structure on the electrochemical and spectroelectrochemical properties of the polymer were also investigated in detail. The results showed that the polymer ﬁlm exhibits multielectrochromic behavior and a low band gap of 1.82 eV.
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