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Bulunan: 319 Adet 0.001 sn
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Erişime Açık

On the Interpretation of Melt Quality Assessment of A356 Aluminum Alloy by the Reduced Pressure Test: The Bifilm Index and Its Physical Meaning

ULUDAĞ, Muhammet | ÇETİN,Remzi | DIŞPINAR, Derya | TİRYAKİOĞLU, Murat

The oxide layer on liquid aluminum serves as a protective property to prevent the alloy from further oxidation. However, it has the potential to be a source of porosity when entrained into the bulk of the liquid. For this reason, oxides entrained into aluminum castings have been shown to degrade casting quality. In the current study, the effectiveness of the reduced pressure test in assessing the quality of A356 alloy melts has been investigated under various conditions obtained by changing six different melt parameters. Several metrics, including average pore size, number density of pores, bi ...Daha fazlası

Erişime Açık

Multiplicity and transverse momentum evolution of charge-dependent correlations in pp, p–Pb, and Pb–Pb collisions at the LHC

KARASU UYSAL, Ayben | ALICE Collaboration

We report on two-particle charge-dependent correlations in pp, p-Pb, and Pb-Pb collisions as a function of the pseudorapidity and azimuthal angle difference, Δη and Δφ respectively. These correlations are studied using the balance function that probes the charge creation time and the development of collectivity in the produced system. The dependence of the balance function on the event multiplicity as well as on the trigger and associated particle transverse momentum (pT) in pp, p-Pb, and Pb-Pb collisions at sNN−−−√=7, 5.02, and 2.76 TeV, respectively, are presented. In the low transverse mome ...Daha fazlası

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MIPs and Aptamers for Recognition of Proteins in Biomimetic Sensing

MENGER, Marcus | YARMAN, Aysu | ERDŐSSY, Júlia | YILDIZ, Hüseyin Bekir | GYURCSÁNYI, Róbert Ervin | SCHELLER, Frieder Wolfram

Biomimetic binders and catalysts have been generated in order to substitute the biological pendants in separation techniques and bioanalysis. The two major approaches use either "evolution in the test tube" of nucleotides for the preparation of aptamers or total chemical synthesis for molecularly imprinted polymers (MIPs). The reproducible production of aptamers is a clear advantage, whilst the preparation of MIPs typically leads to a population of polymers with different binding sites. The realization of binding sites in the total bulk of the MIPs results in a higher binding capacity, however ...Daha fazlası

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Construction of ferrocene modified conducting polymer based amperometric urea biosensor

DERVISEVIC, Muammer | DERVISEVIC, Esma | ŞENEL, Mehmet | ÇEVİK, Emre | YILDIZ, Hüseyin Bekir | ÇAMURLU, Pınar

Herein, an electrochemical urea sensing bio-electrode is reported that has been constructed by fi rstly electropolymerizing 4-(2,5-Di(thiophen-2-yl)-1H-pyrrol-1-yl)aniline monomer (SNS-Aniline) on Pencil Graphite Electrode (PGE), then modifying the polymer coated electrode surface with di-amino-Ferrocene (DAFc) as the mediator, and lastly Urease enzyme through glutaraldehyde crosslinking. The e ff ect of pH, temperature, polymer thickness, and applied potential on the electrode current response was investigated besides performing storage and operational stability experiments with the interferenc ...Daha fazlası

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Synthesis of Various Calix [4] arene Derivatives with Mercaptoalkyl Chains and Their Application in Removing Cr (VI) from Aqueous Solution

SAYIN, Serkan | YILDIZ, Hüseyin Bekir | EYMÜR, Serkan

Four different mercaptoalkyl-substituted calixarene derivatives (5,11,17, 23-tetra-tert-butyl-25,27-bis(3-mercaptopropoxyl)-26,28-dihydroxycalix [4]arene, 25,27-bis(3-mercaptopropoxyl)-26,28-dihydroxycalix[4]arene, 25,27-bis(5-mercaptopentanoxyl)-26,28-dihydroxycalix[4]areneand5,17di-tert-butyl-11,23-di-carboxyl-26,28-bis(3-mercaptopropoxyl)-25,27-dihydroxycalix[4]arene) were synthesized. Their structures were characterized by Fourier transform infrared spectroscopy (FTIR), 1H and 13C NMR spectroscopy, and elemental analysis techniques. Moreover, their extraction capabilities at different para ...Daha fazlası

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Folic-Acid-Modified Conducting Polymer: Electrochemical Detection of the Cell Attachment.

AZAK, Hacer | BARLAS, Fırat Barış | YILDIZ, Hüseyin Bekir | GÜLEÇ, Kadri | DEMİR, Bilal | ODACI DEMİRKOL, Dilek | TİMUR, Suna

Here, postfunctionalization and bioapplication of a π-conjugated polymer named 4-[4H-dithieno(3,2-b:2',3'-d)pyrrol-4-yl]aniline (DTP-aryl-NH2 ) are reported, which is successfully synthesized via electropolymerization onto the glassy carbon electrode. Folic acid (FA) is used to modify the amino functional polymer via N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride/N-hydroxysuccinimide chemistry for the further steps. The selective adhesion of folate receptor positive cells on the surface is followed by the electrochemical methods. Cyclic voltammetry and electrochemical impedance s ...Daha fazlası

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A Novel Architecture Based On A Conducting Polymer And Calixarene Derivative: İts Synthesis And Biosensor Construction

GÖKOĞLAN, Tuğba Ceren | SÖYLEMEZ, Saniye | KESİK, Melis | ÜNAY, Hande | SAYIN, Serkan | YILDIZ, Hüseyin Bekir | ÇIRPAN, Ali | TOPPARE, Levent

In this study, a novel amperometric glucose biosensor based on a selenium comprising conducting polymer and calixarene was developed. Firstly, poly(2-(2-octyldodecyl)-4,7-di(selenoph-2-yl)-2H-benzo[d][1,2,3]triazole), poly((SBTz)) was electrodeposited onto a graphite electrode by an electropolymerization technique. Then, a newly synthesized calixarene and gold nanoparticle (AuNP) mixture was used for the improvement of biosensor characteristics. GOx, as a model enzyme was immobilized on the modified electrode surface. The constructed surface serves as a sufficient immobilization platform for t ...Daha fazlası

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Anisotropic flow of identified particles in Pb-Pb collisions at √sNN = 5.02 TeV

KARASU UYSAL, Ayben | ALICE Collaboration

The elliptic (v2), triangular (v3), and quadrangular (v4) flow coefficients of π±, K±, p+p, Λ+Λ, K0S, and the φ-meson are measured in Pb-Pb collisions at √sNN = 5.02 TeV. Results obtained with the scalar product method are reported for the rapidity range |y| < 0.5 as a function of transverse momentum, pT, at different collision centrality intervals between 0–70%, including ultra-central (0–1%) collisions for π±, K±, and p + p. For pT < 3 GeV/c, the flow coefficients exhibit a particle mass dependence. At intermediate transverse momenta (3 < pT < 8–10 GeV/c), particles show an approximate group ...Daha fazlası

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Calixarene assembly with enhanced photocurrents using P(SNS-NH2)/CdS nanoparticle structure modified Au electrode systems

SAYIN, Serkan | AZAK, Hacer | YILDIZ, Hüseyin Bekir | ÇAMURLU, Pınar | UYSAL AKKUŞ, Gülderen | TOPPARE, Lale | ERSÖZ, Mustafa

Two novel calix[n]arene-adorned gold electrodes producing high photocurrent intensities were successfully constructed by embedding gold electrode surfaces with both P(4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)benzenamine) conducting polymer and 4-mercaptoboronic acid-functionalized semiconductor CdS nanoparticles to facilitate the binding of calix[n]arene sulfonic acids with nanoparticles. This structure enabled an electron transfer cascade that both induced effective charge separation and efficiently generated photocurrent. The prepared electrodes were used to generate photocurrent by relying o ...Daha fazlası

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Charge-dependent flow and the search for the chiral magnetic wave in Pb-Pbcollisionsat√sNN =2.76TeV

KARASU UYSAL, Ayben | ALICE Collaboration

We report on measurements of a charge-dependent flow using a novel three-particle correlator with ALICE in Pb-Pb collisions at the CERN Large Hadron Collider (LHC), and discuss the implications for observation of local parity violation and the chiral magnetic wave (CMW) in heavy-ion collisions. Charge-dependent flow is reported for different collision centralities as a function of the event charge asymmetry. While our results are in qualitative agreement with expectations based on the CMW, the nonzero signal observed in higher harmonics correlations indicates a possible significant background ...Daha fazlası

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The ALICE Transition Radiation Detector: Construction, operation, and performance

KARASU UYSAL, Ayben | ALICE Collaboration

The Transition Radiation Detector (TRD) was designed and built to enhance the capabilities of the ALICE detector at the Large Hadron Collider (LHC). While aimed at providing electron identification and triggering, the TRD also contributes significantly to the track reconstruction and calibration in the central barrel of ALICE. In this paper the design, construction, operation, and performance of this detector are discussed. A pion rejection factor of up to 410 is achieved at a momentum of 1 GeV/c in p-Pb collisions and the resolution at high transverse momentum improves by about 40% when inclu ...Daha fazlası

Erişime Açık

Correlated Event-by-Event Fluctuations of Flow Harmonics in Pb-Pb Collisions at sNN = 2.76 TeV

KARASU UYSAL, Ayben | ALICE Collaboration

We report the measurements of correlations between event-by-event fluctuations of amplitudes of anisotropic flow harmonics in nucleus-nucleus collisions, obtained for the first time using a new analysis method based on multiparticle cumulants in mixed harmonics. This novel method is robust against systematic biases originating from nonflow effects and by construction any dependence on symmetry planes is eliminated. We demonstrate that correlations of flow harmonics exhibit a better sensitivity to medium properties than the individual flow harmonics. The new measurements are performed in Pb-Pb ...Daha fazlası

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