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Construction of conducting polymer/cytochrome C/thylakoid membrane based photo-bioelectrochemical fuel cells generating high photocurrent via photosynthesis

ÇEVİK, Emre | ÇARBAŞ, Buket | ŞENEL, Mehmet | YILDIZ, Hüseyin Bekir

In this study, a photo-bioelectrochemical fuel cell was constructed for photocurrent generation by illuminating the electrodes within an aqueous solution. In this purpose, gold electrode was coated with poly 4-(4H-Dithieno [3,2-b:2′,3′-d]pyrol-4-yl) aniline, P(DTP-Ph-NH2) conductive polymer fi lm by using electrochemical polymerization. Then, P(DTP-Ph-NH2) conductive polymer fi lm coated surface was electrochemically modi fi ed with cytochrome C which covalently linked onto the surface via bis-aniline functionality of the polymer fi lm and formed crosslinked-structure. The thylakoid membrane was a ...Daha fazlası

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Photo-electrochemical communication between cyanobacteria (Leptolyngbia sp.) and osmium redox polymer modified electrodes

KAMRUL, Hasan | YILDIZ, Hüseyin Bekir | SPERLING, Eva | CONGHAILE, Peter Ó | PACKER, Michael A | DÓNAL, Leech | HÄGERHÄLL , Cecilia | GORTON, Lo

Photosynthetic microbial fuel cells (PMFCs) are an emerging technology for renewable solar energy conversion. Major efforts have been made to explore the electrogenic activity of cyanobacteria, mostly using practically unsustainable reagents. Here we report on photocurrent generation (≈8.64 µA cm-2) from cyanobacteria immobilized on electrodes modified with an efficient electron mediator, an Os2+/3+ redox polymer. Upon addition of ferricyanide to the electrolyte, cyanobacteria generate the maximum current density of ≈48.2 µA cm-2. © the Partner Organisations 2014.

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Construction of efficient bioelectrochemical devices: Improved electricity production from cyanobacteria (Leptolyngbia sp.) based on π‐conjugated conducting polymer/gold nanoparticle composite interfaces

ÇEVİK, Emre | BÜYÜKHARMAN, Mustafa | YILDIZ, Hüseyin Bekir

In this study, gold electrodes (GE) were coated with conducting polymers to obtain a high photocurrent using cyanobacteria from a novel bioelectrochemical fuel cell. For this purpose, 4‐(4H‐ditiheno[3,2‐b:2',3'‐d]pyrol‐4‐yl) aniline and 5‐(4H‐dithieno[3,2‐b:2',3'‐d]pyrol‐4‐yl) napthtalane‐1‐amine monomers were coated on GE by performing an electropolymerization process. After that, gold nanoparticles (AuNP) were specifically modified by 2‐mercaptoethane sulfonic acid and p‐aminothiophenol to attach to the electrode surface. The conducting polymers GE coat was modified with functionalized AuNP ...Daha fazlası

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Centrality dependence of particle production in p–Pb collisions at √sNN= 5.02 TeV

KARASU UYSAL, Ayben | ALICE Collaboration

We report measurements of the primary charged-particle pseudorapidity density and transverse momentum distributions in p-Pb collisions at sNN=5.02TeV and investigate their correlation with experimental observables sensitive to the centrality of the collision. Centrality classes are defined by using different event-activity estimators, i.e., charged-particle multiplicities measured in three different pseudorapidity regions as well as the energy measured at beam rapidity (zero degree). The procedures to determine the centrality, quantified by the number of participants (Npart) or the number of n ...Daha fazlası

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Direct photon production at low transverse momentum in proton–proton collisions at √ s = 2.76 and 8 TeV

KARASU UYSAL, Ayben | ALICE Collaboration

Measurements of inclusive and direct photon production at midrapidity in pp collisions at s=2.76 and 8 TeV are presented by the ALICE experiment at the LHC. The results are reported in transverse momentum ranges of 0.4

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Measurement of charged jet production cross sections and nuclear modification in p–Pb collisions at √ sNN = 5.02 TeV

KARASU UYSAL, Ayben | ALICE Collaboration

Charged jet production cross sections in p-Pb collisions at root s(NN) = 5.02 TeV measured with the ALICE detector at the LHC are presented. Using the anti-k(T) algorithm, jets have been reconstructed in the central rapidity region from charged particles with resolution parameters R = 0.2 and R = 0.4. The reconstructed jets have been corrected for detector effects and the underlying event background. To calculate the nuclear modification factor, R-pPb, of charged jets in p-Pb collisions, a pp reference was constructed by scaling previously measured charged jet spectra at root s = 7 TeV. In the ...Daha fazlası

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Event-shape- and multiplicity-dependent identified particle production in pp collisions at 13 TeV with ALICE at the LHC

KARASU UYSAL, Ayben | ALICE Collaboration

Multiplicity-dependent measurements of identified particle production led to the discovery of collective-like behavior in pp collisions at the LHC. Better understanding of the effects attributed to well-understood physics, like multiple hard scatterings, is required to establish whether this behaviour is truly collective in origin. Experimentally, those effects can be controlled using event shapes, like transverse spherocity, which allows the classification of pp collisions either as jetty or isotropic events. The transverse momentum (p(T)) spectra of light-flavor hadrons in pp collisions meas ...Daha fazlası

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ALICE results on system-size dependence of charged-particle multiplicity density in p-Pb, Pb-Pb and Xe-Xe collisions

KARASU UYSAL, Ayben | ALICE Collaboration

Particle production at LHC energies involves the interplay of hard (perturbative) and soft (non-perturbative) QCD processes. Global observables, such as the charged-particle multiplicity, are related to the initial geometry and the energy density produced in the collision. They are important to characterise relativistic heavy-ion collisions and to constrain model calculations. The LHC produced Xenon-Xenon collisions for the first time in October 2017. New results on the primary charged-particle pseudorapidity density, and its pseudorapidity and centrality dependence are presented for this ligh ...Daha fazlası

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Multiplicity dependence of (anti-)deuteron production in pp collisions at s=7TeV

KARASU UYSAL, Ayben | ALICE Collaboration

In this letter, the production of deuterons and anti-deuterons in pp collisions at s=7 TeV is studied as a function of the charged-particle multiplicity density at mid-rapidity with the ALICE detector at the LHC. Production yields are measured at mid-rapidity in five multiplicity classes and as a function of the deuteron transverse momentum (pT). The measurements are discussed in the context of hadron � coalescence models. The coalescence parameter B2, extracted from the measured spectra of (anti-)deuterons and primary (anti-)protons, exhibits no significant pT-dependence for pT

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Testing the system size dependence of hydrodynamical expansion and thermal particle production with π, K, p, and φ in Xe–Xe and Pb–Pb collisions with ALICE

KARASU UYSAL, Ayben | ALICE Collaboration

We present new results on transverse momentum spectra, integrated yields, and mean transverse momenta of pions, kaons, and protons, as well as of phi-mesons for various centrality classes measured in Pb-Pb and Xe-Xe collisions at the LHC. This unique set of data allows us to investigate bulk particle production for very different systems at similar multiplicities. The chemical and kinetic freeze-out parameters are extracted via statistical-thermal and combined blast-wave fits to the data in heavy-ion collisions and are compared to results obtained in pp and p-Pb collisions at similar multiplic ...Daha fazlası

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Measurements of anisotropic flow and flow fluctuations in Xe–Xe and Pb–Pb collisions with ALICE

KARASU UYSAL, Ayben | ALICE Collaboration

Anisotropic flow is a key observable to characterise the system created in heavy-ion collisions, as it is sensitive to the system's initial state, transport properties, the equation of state and freeze-out conditions. In these proceedings we present the anisotropic flow coefficients of inclusive charged particles in Pb-Pb collisions at root s(NN) = 2.76 and 5.02 TeV, and in Xe-Xe collisions at root s(NN) = 5.44 TeV. The results are reported for a wide range of particle transverse momentum within the pseudo-rapidity range vertical bar eta vertical bar < 0.8 at different collision centralities. ...Daha fazlası

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Energy and system dependence of nuclear modification factors of inclusive charged particles and identified light hadrons measured in p-Pb, Xe-Xe and Pb-Pb collisions with ALICE

KARASU UYSAL, Ayben | ALICE Collaboration

We report recent ALICE results on primary charged particle and neutral meson production in pp, p-Pb, Pb-Pb and Xe-Xe collisions at LHC energies. In this article, measurements of the nuclear modification factors RAA of primary charged particles and of light neutral mesons in Pb-Pb, in Xe-Xe and in p-Pb collisions in a wide p(T) range and different centrality classes are discussed. We compare the nuclear modification factors obtained for different collision systems as a function of transverse momentum, collision centrality as well as charged particle multiplicity (dN(ch)/d eta). We also present ...Daha fazlası

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